عنوان
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Colorimetric and fluorimetric chemosensor based on upper rim-functionalized calix [4] arene for selective detection of fluoride ion
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نوع پژوهش
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مقاله چاپ شده
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کلیدواژهها
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Calix[4]arene; Chromogenic; Fluorogenic sensor; Fluoride; Sulfonamide-fluorenone
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چکیده
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A new colorimetric and fluorescent chemosensor for fluoride anion based on calix [4]arene bearing four sulfonamide-fluorenone subunits on the upper rim was conveniently synthesized. It showed a remarkable color change as well as the fluorescence quenching upon addition of F− even in the presence of a wide range of anions in DMSO. The binding property of L with F− was studied by a combination of various spectroscopic techniques, such as absorption and emission titration, Job's plot and 1 H NMR titration. It is anticipated that this design with functional group attached to upper rim of calix[4]arene platform can provide a new approach for the development of F− chemosensor.
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پژوهشگران
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مریم مهاجرانی (نفر سوم)، رحمان حسین زاده (نفر دوم)، محمد نعمتی (نفر اول)
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