عنوان
|
A mild and efficient method for the conversion of aldehydes into nitriles and thiols into disulfides using an ionic liquid oxidant
|
نوع پژوهش
|
مقاله چاپ شده
|
کلیدواژهها
|
Hexamethylene bis(N-methylimidazolium) bis(dichloroiodate), Ionic liquid oxidant, Nitriles, Disulfides, Oxidation
|
چکیده
|
A simple, mild and high yielding method for the conversion of various aldehydes to nitriles has been developed using an ionic liquid reagent, hexamethylene bis(N-methylimidazolium) bis(dichloroiodate) (HMBMIBDCI), in combination with aqueous ammonia in CH3CN at room temperature. Moreover, the treatment of aromatic and aliphatic thiols with HMBMIBDCI resulted in the corresponding disulfides in solvent-free condition at room temperature.
|
پژوهشگران
|
محبوبه نوذریان (نفر سوم)، حمید گلچوبیان (نفر دوم)، رحمان حسین زاده (نفر اول)
|