عنوان
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Synthesis, structural characterization and chromotropism of a Copper(II) complex containing bidentate ligand
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نوع پژوهش
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مقاله چاپ شده
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کلیدواژهها
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Diamine ligand, Copper(II) complex, Thermochromism, solvatochromism, Ionochromism, Halochromism
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چکیده
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A new coordination compound, [Cu(L)2(OH2)](ClO4)2 where, L = N-(pyridin-2-ylmethyl)propane-2-amine was prepared and characterized by elemental analysis, molar conductance and IR and UV-Vis spectroscopy techniques. X-ray crystal analysis of the complex confirmed that the copper(II) ion has a distorted square pyramidal environment. The complex is chromotropic in solution. Chromotropism properties of the complex including solvato-, thermo-, halo-, and ionochromism were investigated in detail. The complex displayed strongly pronounced reversible thermochromism in solution due to dissociation and of re-coordination of water molecule.
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پژوهشگران
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گیسپه برونو (نفر چهارم)، احسان رضایی (نفر سوم)، محبوبه ترحمی اسبو (نفر دوم)، حمید گلچوبیان (نفر اول)
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