عنوان
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Organosulfur phosphonium salt-mediated synthesis of functionalized thiopyran derivatives
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نوع پژوهش
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مقاله چاپ شده
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کلیدواژهها
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Methyl 4-oxotetrahydro-2H thiopyran-3-carboxylate, Wittig reaction, dialkyl acetylenedicarboxylates, phosphorus ylides, triphenylphosphine
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چکیده
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Methyl 4-oxotetrahydro-2H-thiopyran-3-carboxylate as a CH-acid undergoes amild reactionwith acetylenic esters in the presence of triphenylphosphine to produce phosphorus ylides possessing thiopyran-4-one ring moiety. The resulted phosphorus ylides when heated in toluene aforded functionalized thiopyran derivatives through intramolecular Wittig reaction.
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پژوهشگران
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سکینه اصغری قراخیلی (نفر اول)، محمود تاجبخش (نفر سوم)، قاسم فیروز زاده پاشا (نفر دوم)
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