مشخصات پژوهش

صفحه نخست /Chemoselective and Efficient ...
عنوان Chemoselective and Efficient Method for Deprotection of THP and Silyl Ethers with H2O2/ Mn(III) Schiff-base Complex
نوع پژوهش مقاله چاپ شده
کلیدواژه‌ها THP ether, silyl ether, deprotection, Mn(III) Schiff-base complex, hydrogen peroxide.
چکیده Mn(III) Schiff-base complex as a catalyst with H2O2 was applied for oxidative deprotection of THP ethers to the corresponding carbonyl compounds and conversion of silyl ethers into the parent alcohols under mild conditions. Chemoselective cleavage of trimethylsilyl ethers in the presence of t-butyldimethylsilyl ethers and cleavage of trimethylsilyl ethers in the presence of tetrahydropyranyl ethers were also achieved with this system.
پژوهشگران راحله رضویان (نفر چهارم)، حمید گلچوبیان (نفر سوم)، رحمان حسین زاده (نفر دوم)، محمود تاجبخش (نفر اول)