عنوان
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Synthesis of Dinuclear Thiolate-Bridged Macrocyclic Nickel(II) Complexes with C2 Linker Diimine
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نوع پژوهش
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مقاله چاپ شده
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کلیدواژهها
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dinuclear nickel(II) complex, macrocyclic ligand, cyano group, diamagnetic Ni(II) complex
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چکیده
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Macrocyclic dinickel(II) complexes derived from 2,6-diformyl-4-methyl-thiophenolate and C2 linking diamine(diaminomalleonitrile ethylenediamine) are prepared and characterized. In these complexes, both metal centers in the N2S2 sites are in square-planar configuration and are diamagnetic. The low-spin states of the nickel(II) ions are preserved in polar solvents.
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پژوهشگران
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حمید گلچوبیان (نفر دوم)، فاطمه فرسوی (نفر اول)
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