|
Title
|
Crystal and Molecular Structure of a Cu(II) Complex with Macrocyclic Ligand of 10,12-dibromo-6-ethylcyanide-3,6,14,18-tetraazapentaicosa-1(25), 8(24),10,12,13,19,21,23-octaene-24,25-diol
|
|
Type
|
JournalPaper
|
|
Keywords
|
Crystal Structure, Cu(II) Complex, Macrocyclic Ligand
|
|
Abstract
|
The crystal structure of the title compound was determined by single-crystal X-ray diffraction. The compound crystallizes in a monoclinic system and was characterized thus: P21/n, a = 8.6189(2)Å, b = 17.9591(7)Å, c = 18.4009(6) Å, b = 102.2560(19)˚, Z = 4, V = 2783.32(16)Å3. In the mono nuclear macrocyclic complex the copper(II) ion resides at the N(imine)2O2 coordination site, whereas the other compartment, N(amine)2O2, is occupied by a proton. The geometry around copper(II) is square-planar.
|
|
Researchers
|
Davod Sadeghi FATEH (Second Researcher), Hamid Golchoubian (First Researcher)
|