عنوان
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Electrocatalytic determination of l-cysteine using a modified carbon nanotube paste electrode: Application to the analysis of some real samples
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نوع پژوهش
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مقاله چاپ شده
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کلیدواژهها
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L-Cysteine; Carbon paste electrode; Carbon nanotubes; Voltammetry
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چکیده
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The electrooxidation of L-cysteine (L-Cys) was studied using a benzoylferrocene (BF) modified multi-wall carbon nanotube paste electrode (BFCNPE) using cyclic voltammetry (CV), square wave voltammetry (SWV) and chronoamperometry (CHA). Under optimum pH in CV the oxidation of L-Cys occurs at a potential about 215 mV less positive than that at the surface of unmodified carbon paste electrode. The catalytic oxidation peak currents were dependent on the L-Cys concentration and a linear calibration curve was obtained in the range 0.7–350.0 mmol/L of L-Cys with SWV method. The detection limit (3s) was determined as 0.1 mmol/L. This method was also used for the determination of L-Cys in some real samples.
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پژوهشگران
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رحمان حسین زاده (نفر چهارم)، هادی بیت اللهی (نفر سوم)، محمد علی طاهر (نفر دوم)، ملیحه احمدی پور (نفر اول)
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