عنوان
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Determination of L-cysteine Based on its Potentiometric Effect on a Belousov-Zhabotinskii Oscillating Chemical Reaction,
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نوع پژوهش
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مقاله چاپ شده
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کلیدواژهها
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L-cysteine, Belousov-Zhabotinskii (BZ) reaction, oscillating chemical reaction, potentiometric, statistical experimental design, Box-Behnken design
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چکیده
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Here, a simple and convenient method with suitable selectivity and high sensitivity for the determination of L-cysteine based on Belousov-Zhabotinskii (B-Z) oscillating chemical reaction is presented. The addition of L-cysteine to the oscillating system increased the oscillating period. This increasing in oscillating period is used as the analytical signal for determination of L-cysteine. The optimum conditions for the determination of L-cysteine were also investigated through a three-level Box-Behnken design. The analytical signal was linearly proportional to the logarithm of the L-cysteine concentration over the range of 4.0 × 10 -7 to 3.0 × 10 -5 M under optimum conditions. The detection limit was estimated 4.0 × 10 -7 M and relative standard deviation (RSD) for five measurements of 5.0 × 10 -6 M L-cysteine was 3.4٪.
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پژوهشگران
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اکرم السادات حمیدی (نفر پنجم)، فریده سخاوی (نفر چهارم)، رضا اوجانی (نفر سوم)، ابوالفضل کیانی (نفر دوم)، جهانبخش رئوف (نفر اول)
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