عنوان
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Investigation of the catalytic effect of copper (II) complex with N,N-Bis[1(2)H-tetrazole-5-yl] amine ligand on thermal decomposition of ammonium perchlorate
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نوع پژوهش
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مقاله ارائه شده
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کلیدواژهها
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Ammonium perchlorate, Catalysis, Tetrazole, Thermal decomposition
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چکیده
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In this research, copper(II) complex with N,N-bis[1(2)H-tetrazol-5-yl]amine ligand (H₂BTA) was prepared on thermal decomposition of ammonium perchlorate and was detected used by different methods such as Fourier transform infrared spectroscopy (FT-IR), X-ray diffraction (XRD) and then its catalytic effect was investigated by using thermal gravimetric (TG-DSC). Specifically, a coordination polymer with a tetrazole containing ligand such as [Cu(BTA)(NH₃)₂] was synthesized as a catalyst for the first time to investigate the thermal decomposition of AP. Investigating the effect of this catalyst on thermal decomposition temperature of ammonium perchlorate with different ratios of 97%, 96%, 93% AP shows that the catalyst has a good catalytic duty in the process of reducing the decomposition temperature and increasing the released energy of ammonium perchlorate.
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پژوهشگران
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عباس اسلامی (نفر دوم)، مهدیه کریمی (نفر اول)
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