مشخصات پژوهش

عنوان	F€orster resonance energy transfer-based molecularly imprinted polymer /amine-functionalized metal-organic framework nanocomposite for trace level detection of 4-nitropheno
نوع پژوهش	مقاله چاپ شده
کلیدواژه‌ها	Luminescent metal-organic frameworkOptical, sensor, 4-Nitrophenol, Molecularly imprinted polymer, Fluorescence quenching, Nanocomposite
چکیده	Herein, luminescent metal-organic framework (LMOF) is modified with molecularly imprinted polymer (MIP) and employed as an efficient and cost-effective nanoprobe for the determination of 4-nitrophenol (4-NP). Amine-UiO-66 support with unique luminescence property is chosen for creating the template of 4-NP using MIP to construct a highly selective LMOF-based sensor (amine-UiO-66/MIP nanocomposite). The imprinted sites formed at the surface of LMOF significantly enhance the selectivity of the probe for 4-NP over its analogs. 4-NP can effectively quench the fluorescent intensity of the optical sensor via the Förster resonance energy transfer (FRET) mechanism. Amine-UiO-66/MIP sensor provided the linear range of 0.05–50 μM and low limit of detection of 0.009 μM for sensing of 4-NP. The application of probe for the fluorometric analysis of real samples, including drinking and environmental water, provided satisfactory recovery results with low relative standard deviation (RSD).
پژوهشگران	سید ناصر عزیزی (نفر سوم)، شهرام قاسمی میر (نفر دوم)، فاطمه امیری پور (نفر اول)