The surface modification of cotton samples was carried out using a liquid (ethanol) electrosprayassisted
atmospheric pressure plasma jet. X-ray photoelectron spectroscopy (XPS) and Raman
analysis confirmed the successful deposition of diamond like carbon (DLC) nano structures on the
cotton surface. The super hydrophobic state of the samples was probed by contact angle
measurements. The water repellency of the layers was tuned by controlling the voltage applied to the
electrospray electrode. An investigation of the morphological and chemical structures of the samples
by field emission scanning microscopy, atomic force microscopy (AFM) and XPS indicated that the
physical shape, distribution and amorphization of the DLC structures were successfully adjusted and
improved by applying a voltage to the electrospray electrode. Finally wash durability of the best
sample was tested for 35 cycles. In this work, the use of a well-developed atmospheric pressure
plasma jet for DLC nano structures deposition can enable a promising environmentally friendly and
low-cost approach for modifying cotton fabrics for super water-repellent fabric applications.