A mild and efficient method for the conversion of aldehydes into nitriles and thiols into disulfides using an ionic liquid oxidant

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عنوان	A mild and efficient method for the conversion of aldehydes into nitriles and thiols into disulfides using an ionic liquid oxidant
نوع پژوهش	JournalPaper
کلیدواژه‌ها	Hexamethylene bis(N-methylimidazolium) bis(dichloroiodate), Ionic liquid oxidant, Nitriles, Disulfides, Oxidation
سال	2015
مجله	RESEARCH ON CHEMICAL INTERMEDIATES
شناسه DOI
پژوهشگران	Rahman Hosseinzadeh ، Hamid Golchoubian ، Mahboobe Nouzarian

چکیده

A simple, mild and high yielding method for the conversion of various aldehydes to nitriles has been developed using an ionic liquid reagent, hexamethylene bis(N-methylimidazolium) bis(dichloroiodate) (HMBMIBDCI), in combination with aqueous ammonia in CH3CN at room temperature. Moreover, the treatment of aromatic and aliphatic thiols with HMBMIBDCI resulted in the corresponding disulfides in solvent-free condition at room temperature.

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چکیده