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Sayed Reza Hosseini-zavvarmahalleh

Sayed Reza Hosseini-zavvarmahalleh

Academic rank: Associate Professor
ORCID:
Education: PhD.
ScopusId:
HIndex:
Faculty: Faculty of Chemistry
Address: Nanochemistry Research Laboratory, Faculty of Chemistry, University of Mazandaran, Postal Code: 47416-95447, Babolsar, Iran
Phone: 01135302361

Research

Title
Preparation of CuO/NiO composite nanofibers by electrospinning and their application for electro-catalytic oxidation of hydrazine
Type
JournalPaper
Keywords
Electrospinning; Composite nanofibers; Copper oxide/nickel oxide; Hydrazine hydrate; Electro-catalysis
Year
2017
Journal JOURNAL OF POWER SOURCES
DOI
Researchers Sayed Reza Hosseini-zavvarmahalleh ، Shahram Ghasemi ، Mina Kamali-Rousta

Abstract

In present work, polyvinyl alcohol/copper acetate-nickel acetate composite nanofibers (PVA/Cu(OAc)2-Ni(OAc)2 NFs) with various weight percentages of Cu(OAc)2:Ni(OAc)2 such as 25:75, 50:50 and 75:25 are fabricated by electrospinning method. After this, the CuO/NiO composite NFs are produced after thermal treatment. A calcination temperature at about 600 oC is determined by thermal gravimetric analysis. Field-emission scanning electron microscopy (FE-SEM) for morphology characterization indicates that large quantities of the prepared PVA/Cu(OAc)2-Ni(OAc)2 composite fibers have smooth and bead-free surfaces. Fourier transform infrared spectroscopy, FE-SEM and energy dispersive X-ray spectroscopy are used to characterize the CuO/NiO composites. According to FE-SEM results, with increasing of Cu(OAc)2 content in polymeric solution, the fibers don’t remain as continuous structures after calcination and accumulate in the form of nanoparticles. Also, a carbon paste electrode (CPE) bulky modified with CuO/NiO composites is used for investigation of the electro-catalytic oxidation of hydrazine hydrate in NaOH solution. The catalytic activities of the synthesized catalysts are studied through cyclic voltammetry, chronoamperometry and electrochemical impedance spectroscopy. The obtained results demonstrate that the most appropriate proportion of Cu(OAc)2:Ni(OAc)2 in electrospinning solution to enhance the electro-catalytic ability is 25:75.