1402/12/05

سید ناصر عزیزی

مرتبه علمی: استاد
ارکید:
تحصیلات: دکترای تخصصی
اسکاپوس:
دانشکده: دانشکده شیمی
نشانی: ایران مازندران دانشکده شیمی گروه تجزیه
تلفن: 09111144457

مشخصات پژوهش

عنوان
F€orster resonance energy transfer-based molecularly imprinted polymer /amine-functionalized metal-organic framework nanocomposite for trace level detection of 4-nitropheno
نوع پژوهش
JournalPaper
کلیدواژه‌ها
Luminescent metal-organic frameworkOptical, sensor, 4-Nitrophenol, Molecularly imprinted polymer, Fluorescence quenching, Nanocomposite
سال
2022
مجله ANALYTICA CHIMICA ACTA
شناسه DOI
پژوهشگران Seyed Naser Azizi ، Shahram Ghasemi ، Fatemeh Amiripour

چکیده

Herein, luminescent metal-organic framework (LMOF) is modified with molecularly imprinted polymer (MIP) and employed as an efficient and cost-effective nanoprobe for the determination of 4-nitrophenol (4-NP). Amine-UiO-66 support with unique luminescence property is chosen for creating the template of 4-NP using MIP to construct a highly selective LMOF-based sensor (amine-UiO-66/MIP nanocomposite). The imprinted sites formed at the surface of LMOF significantly enhance the selectivity of the probe for 4-NP over its analogs. 4-NP can effectively quench the fluorescent intensity of the optical sensor via the Förster resonance energy transfer (FRET) mechanism. Amine-UiO-66/MIP sensor provided the linear range of 0.05–50 μM and low limit of detection of 0.009 μM for sensing of 4-NP. The application of probe for the fluorometric analysis of real samples, including drinking and environmental water, provided satisfactory recovery results with low relative standard deviation (RSD).