Title
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TiO<sub>2</sub> NPs as Catalyst for N-Formylation and N-Acetylation of Amines under Solvent–Free Conditions
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Type
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JournalPaper
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Keywords
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TiO2- nanoparticles, N-formylation, N-acetylation, formamides, acetamides, solvent-free
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Abstract
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Anatase phase TiO2- nanoparticles (TiO2 NPs) used as a heterogeneous and highly efficient catalyst for the synthesis of formamides and acetamides by reacting the structurally diverse amines with formic acid and acetic anhydride or acetic acid, respectively, under solvent-free conditions at room temperature. Chemoselectivity, mild and heterogeneous conditions, clean work-up and high reaction yields make this method practical for organic transformations.
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Researchers
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Mahgol Tajbakhsh (Fifth Researcher), Parizad Rezaei (Fourth Researcher), Heshmatollah Alinezhad (Third Researcher), Rahman Hosseinzadeh (Second Researcher), mahmood tajbakhsh (First Researcher)
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