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Title
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Electrocatalytic oxidation of thiosulfate at 2,7-bis(ferrocenylethyl)-fluoren-9-one-modified carbon paste electrode (2,7-BFEFMCPE): Application to the catalytic determination of thiosulfate in real sample
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Type
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JournalPaper
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Keywords
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2,7-Bis(ferrocenylethyl)-fluoren-9-one; Thiosulfate; Electrocatalysis; Cyclic voltammetry; Differential pulse voltammetry
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Abstract
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Electrocatalytic oxidation of thiosulfate at the 2,7-BFEFMCPE occurs at a potential about 460 mV less positive than that unmodified carbon paste electrode. The diffusion coefficient (=5.6×10-5 cm2 s-1), the kinetic parameters such as electron transfer coefficient, (=0.5) and Kh(=1.21×10-3cm s-1) of thiosulfate oxidation at the surface of, 2,7-BFEFMCPE were determined. The electrocatalytic oxidation peak current of thiosulfate showed two linear dynamic ranges (0.0006–0.009 mmol/L and 0.009–0.900 mmol/L) and a detection limit of 0.00015 mmol/L. This method was also examined as a new electrochemical sensor for the determination of thiosulfate in real sample.
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Researchers
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Hassan Karimi-Maleh (Third Researcher), Reza Ojani (Second Researcher), Jahan Bakhsh Raoof (First Researcher)
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