20 خرداد 1402
محمود تاجبخش

محمود تاجبخش

مرتبه علمی: استاد
نشانی: ایران- استان مازندران- شهرستان بابلسر- دانشگاه مازندران- دانشکده شیمی
تحصیلات: دکترای تخصصی / شیمی آلی
تلفن: 09111146981
دانشکده: دانشکده شیمی

مشخصات پژوهش

عنوان preparation, characterization and application of nanosized CuO/HZSM-5 as an efficient and heterogeneous catalyst for theN-formylation of amines at room temperature
نوع پژوهش مقاله چاپ شده
کلیدواژه‌ها
CuO/HZSM-5, Heterogeneous catalyst, N-Formylation, Solvent-free
مجله JOURNAL OF COLLOID AND INTERFACE SCIENCE
شناسه DOI /doi: 10.1016/j.jcis.2016.02.062
پژوهشگران محمود تاجبخش (نفر اول) ، حشمت اله علی نژاد (نفر دوم) ، محمود نصرالله زاده (نفر سوم) ، تقی عزیز کمالی (نفر چهارم)

چکیده

An efficient and new method for the synthesis of formamides using HZSM-5 zeolite supported copper oxide nanoparticles as an efficient and heterogeneous catalyst is reported. The catalyst was characterized by X-ray diffraction (XRD), field emission scanning electron microscopy (FE-SEM), transmission electron microscopy (TEM), atomic absorption spectroscopy (AAS), Brunauer-Emmett-Teller (BET), energy disper-sive X-ray spectroscopy (EDS), temperature programmed desorption of ammonia (TPD-NH3) and Fourier transformed infrared spectroscopy (FT-IR). This method has the advantages of eliminating homogeneous catalysts and provides simple methodology with easy work up. Excellent yields of the corresponding for-mamides were obtained through this cost-effective protocol under solvent-free conditions with shorter reaction time. The catalyst was easily isolated from the reaction mixture by filtration and reused several times without significant loss in its catalytic