20 خرداد 1402
محمود تاجبخش

محمود تاجبخش

مرتبه علمی: استاد
نشانی: ایران- استان مازندران- شهرستان بابلسر- دانشگاه مازندران- دانشکده شیمی
تحصیلات: دکترای تخصصی / شیمی آلی
تلفن: 09111146981
دانشکده: دانشکده شیمی

مشخصات پژوهش

عنوان Synthesis and characterization of N-hydroxyphthalimide immobilized on SiO2-coated Fe3O4 nanoparticles as magnetic catalyst for oxidation of benzyl alcohols and hydrocarbons
نوع پژوهش مقاله چاپ شده
کلیدواژه‌ها
N-Hydroxyphthalimide; Nanomagnetic catalyst; Oxidation; Hydrogen peroxide; Benzyl alcohols; Hydrocarbons
مجله Journal of the Iranian Chemical Society
شناسه DOI https://doi.org/10.1007/s13738-017-1288-5
پژوهشگران رحمان حسین زاده (نفر اول) ، محمد مواجی (نفر دوم) ، محمود تاجبخش (نفر سوم) ، زهرا لاسمی (نفر چهارم)

چکیده

In this study, N-hydroxyphthalimide (NHPI) was successfully attached on functionalized SiO2 coated Fe3O4 nanoparticles through amid bond. The sustained nanomagnetite-immobilized NHPI as a new magnetically recoverable catalyst was characterized by FT-IR, XRD, TGA, VSM, TEM and SEM techniques. The prepared catalyst exhibited high selectivity for oxidation of various benzyl alcohols and hydrocarbons in the presence of hydrogen peroxide as oxidant. The catalyst can be readily separated from the reaction mixture using an external magnet and reused several times without significant loss of its catalytic activity.