عبد الرئوف صمدی میبدی

This study demonstrates an inverted energy-gradient hybrid nanoparticle architecture that supports the formation of 2D excitons in the nanoshell domain. The developed geometry places a wide-gap semiconductor quantum dot (ZnS, Eg= 3.68 eV) at the core of the nanocomposite particle in order to funnel the photoinduced energy into the low-gap (CdS, Eg= 2.42 eV) shell layer. This inverted band regime helps to extract the photogenerated excitons into the shell and hence increases the exciton transport quantum efficiency, hereby leading to the superior photocatalytic efficiency for photoredox reactions over the nanohybrid. To demonstrate bandgap engineering and photoinduced charge carrier delocalization, we employed steady-state and time-resolved emission and absorption techniques in the presence and absence of an electron quencher (4- nitrophenol) and hole quencher (4-methoxyphenol). The significant suppression of band-edge emissions and the decrement of the fluorescence lifetimes demonstrated the key role of nanoshell on the transfer of photogenerated charge carriers from core to the surface of the photocatalyst. Detailed investigations of the photocatalytic activity of ZnS@CdS and kinetic study of the reactions were also carried out under solar radiation. The contribution of O 2 *@ and *OH to photocatalytic reactions revealed respectively via luminol chemiluminescence and terephthalic acid photoluminescence techniques.