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Abbasali Rostami

Abbasali Rostami

Academic rank: Professor
ORCID:
Education: PhD.
ScopusId:
HIndex:
Faculty:
Address: Dept. of Physical Chemistry, Faculty of Chemistry, University of Mazandaran
Phone: 911215706

Research

Title
Chemical synthesis, characterization and electro-oxidation of hydrazine via a carbon paste electrode modified with poly (P-phenylendiamine/Al2O3) nanocomposite
Type
JournalPaper
Keywords
Hydrazine oxidation Nanocomposite Nanostructure materials Electro-catalyst
Year
2012
Journal Electrochimica acta
DOI
Researchers Abbas Emamgholizadeh ، Abdollah Omrani ، Abbasali Rostami

Abstract

In this article, the chemical synthesis and characterization of Al2O3 nanoparticles dispersed into poly (P-phenylendiamine) (PpDP) was reported. The morphology, conductivity and structure of the nanocomposite was characterized by scanning electron microscopy (SEM), four probe testing and XRD experiment, respectively. Catalytic activity and stability for the oxidation of hydrazine were studied by using cyclic voltammetry and electrochemical impedance spectroscopy (EIS). The results show that the nanocomposite significantly enhances the effective surface area and the catalytic activity of the CPE (carbon paste electrode) for oxidation of hydrazine. The results obtained confirmed that the dispersion of the Al2O3 particles is connected with catalytic response to a higher activity. The nanotubular morphology of poly (P-phenylendiamine) helps in the effective dispersion of Al2O3 particles facilitating the easier access of hydrazine to the catalytic sites. The poly (P-phenylendiamine) nanotubes modified with Al2O3 nanoparticles cause a great increase in electroactivity and the electro-catalytic properties of CPE for hydrazine oxidation.