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Rahman Hosseinzadeh

Rahman Hosseinzadeh

Academic rank: Professor
ORCID:
Education: PhD.
ScopusId:
Faculty: Faculty of Chemistry
Address: Department of Organic Chemistry, Faculty of Chemistry, University of Mazandaran, Babolsar, Iran
Phone: 01135302356

Research

Title
A mild and efficient method for the conversion of aldehydes into nitriles and thiols into disulfides using an ionic liquid oxidant
Type
JournalPaper
Keywords
Hexamethylene bis(N-methylimidazolium) bis(dichloroiodate), Ionic liquid oxidant, Nitriles, Disulfides, Oxidation
Year
2015
Journal RESEARCH ON CHEMICAL INTERMEDIATES
DOI
Researchers Rahman Hosseinzadeh ، Hamid Golchoubian ، Mahboobe Nouzarian

Abstract

A simple, mild and high yielding method for the conversion of various aldehydes to nitriles has been developed using an ionic liquid reagent, hexamethylene bis(N-methylimidazolium) bis(dichloroiodate) (HMBMIBDCI), in combination with aqueous ammonia in CH3CN at room temperature. Moreover, the treatment of aromatic and aliphatic thiols with HMBMIBDCI resulted in the corresponding disulfides in solvent-free condition at room temperature.