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Rahman Hosseinzadeh

Rahman Hosseinzadeh

Academic rank: Professor
ORCID:
Education: PhD.
ScopusId:
Faculty: Faculty of Chemistry
Address: Department of Organic Chemistry, Faculty of Chemistry, University of Mazandaran, Babolsar, Iran
Phone: 01135302356

Research

Title
Electrochemical behavior of isoproterenol in the presence of uric acid and folic acid at a carbon paste electrode modified with 2,7-bis(ferrocenyl ethyl)fluoren-9-one and carbon nanotubes
Type
JournalPaper
Keywords
Isoproterenol .Uric acid.Folic acid.Modified electrode. Electrocatalysis. Carbon nanotubes
Year
2012
Journal Journal of Solid State Electrochemistry
DOI
Researchers Hadi Beitollahi ، Jahan Bakhsh Raoof ، Hassan Karimimaleh ، Rahman Hosseinzadeh

Abstract

This paper reports the selective determination of isoproterenol (IP) in the presence of uric acid (UA) and folic acid (FA) using 2,7-bis(ferrocenyl ethyl)fluoren-9-one modified carbon nanotube paste electrode (2,7-BFCNPE) in 0.1 M phosphate buffer solution (PBS) (pH 7.0). The bare carbon paste electrode does not separate the voltammetric signals of IP, UA, and FA. However, 2,7-BFCNPE not only resolved the voltammetric signals of IP, UA, and FA with potential differences of 150, 325, and 475 mV between IP– UA, UA–FA, and IP–FA, respectively, but also dramatically enhanced the oxidation peak currents of them when compared to bare carbon paste electrode. In PBS of pH 7.0, the oxidation current increased linearly with two concentration intervals of IP, one is 0.08 to 17.5μM and the other is 17.50 to 700.0 μM. The detection limit (3σ) obtained by DPV was 26.0±2 nM. The practical application of the modified electrode was demonstrated by determining IP in IP injection, urine, and human blood serum.