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Rahman Hosseinzadeh

Rahman Hosseinzadeh

Academic rank: Professor
ORCID:
Education: PhD.
ScopusId:
Faculty: Faculty of Chemistry
Address: Department of Organic Chemistry, Faculty of Chemistry, University of Mazandaran, Babolsar, Iran
Phone: 01135302356

Research

Title
IONIC LIQUID IODINATING REAGENT FOR MILD AND EFFICIENT IODINATION OF AROMATIC AND HETEROAROMATIC AMINES AND TERMINAL ALKYNES
Type
JournalPaper
Keywords
Aromatic and heteroaromatic amines; hexamethylene bis(N-methylimidazolium) bis(dichloroiodate); iodination; ionic liquid; terminal alkynes
Year
2013
Journal Synthetic Communications
DOI
Researchers Mahboobe Nouzarian ، Rahman Hosseinzadeh ، Hamid Golchoubian

Abstract

Hexamethylene bis(N-methylimidazolium) bis(dichloroiodate) (HMBMIBDCI), an ionic liquid iodinating reagent, have been prepared and characterized. Its ability to perform iodination reactions with a variety of substrates has been explored. In general, iodination reactions of aromatic and heteroaromatic amines proceed with good yields in the absence of solvent. Reactions of terminal alkynes in the presence of 1,8-diazabicyclo [5.4.O] undec-7-ene and tetrahydrofuran have been investigated as well. [Supplementary materials are available for this article. Go to the publisher’s online edition of Synthetic Communications1 for the following free supplemental resource: Full experimental and spectral details.]