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Rahman Hosseinzadeh

Rahman Hosseinzadeh

Academic rank: Professor
ORCID:
Education: PhD.
ScopusId:
Faculty: Faculty of Chemistry
Address: Department of Organic Chemistry, Faculty of Chemistry, University of Mazandaran, Babolsar, Iran
Phone: 01135302356

Research

Title
Chemoselective and Efficient Method for Deprotection of THP and Silyl Ethers with H2O2/ Mn(III) Schiff-base Complex
Type
JournalPaper
Keywords
THP ether, silyl ether, deprotection, Mn(III) Schiff-base complex, hydrogen peroxide.
Year
2008
Journal Letters in Organic Chemistry
DOI
Researchers mahmood tajbakhsh ، Rahman Hosseinzadeh ، Hamid Golchoubian ، Raheleh Razavian

Abstract

Mn(III) Schiff-base complex as a catalyst with H2O2 was applied for oxidative deprotection of THP ethers to the corresponding carbonyl compounds and conversion of silyl ethers into the parent alcohols under mild conditions. Chemoselective cleavage of trimethylsilyl ethers in the presence of t-butyldimethylsilyl ethers and cleavage of trimethylsilyl ethers in the presence of tetrahydropyranyl ethers were also achieved with this system.