We used the cluster structure properties of the 212Po to estimate the neutron skin thickness of 208Pb. For this purpose, we considered two important components: (a) alpha decay is a low energy phenomenon; therefore, one can expect that the mean-field, which can explain the ground state properties of 212Po, does not change during the alpha decay process. (b) 212Po has a high alpha cluster-like structure, two protons and two neutrons outside its core nucleus with a double magic closed-shell, and the cluster model is a powerful formalism for the estimation of alpha decay preformation factor of such nuclei. The slope of the symmetry energy of 208Pb is estimated to be MeV within the selected same mean-fields and Skyrme forces, which can simultaneously satisfy the ground-state properties of parent and daughter nuclei, as their neutron skin thicknesses are consistent with experimental data.