One new dinuclear copper(II) complex with empirical formula [Cu(L)(µ-OH)]2(PF6)2, where L=N-(pyridin-2-ylmethyl)cyclohexanamine was prepared and characterized by molar conductance and spectral studies. Characterization results showed that in the homoleptic complex the copper(II) centers are five coordinated with square pyramidal structures that a water molecule or a counter ion coordinated on the apex of each copper(II) ions. The complex is solvatochromic and its solvatochromism property of was investigated by visible spectroscopy. The complex is fairly soluble in a large number of organic solvents and show positive solvatochromism. The solvatochromism properties is due to coordination of the solvent molecules on the top and below of the molecular plane.