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Heshmatollah Alinezhad

Heshmatollah Alinezhad

Academic rank: Professor
ORCID:
Education: PhD.
ScopusId:
Faculty: Faculty of Chemistry
Address:
Phone: 9111144735

Research

Title
Synthesis of the first nano ionic liquid 1- methylimidazolium trinitromethanide {[HMIM] C(NO2)3} and its catalytic use for Hanztsch fourcomponent condensation
Type
JournalPaper
Keywords
nano ionic liquid 1- methylimidazolium trinitromethanide {[HMIM] C(NO2)3}, Hanztsch
Year
2014
Journal RSC Advances
DOI
Researchers Mohammad Ali Zolfigol ، Saeed Baghery ، Ahmad Reza Moosavi-Zare ، Seyed Mohammad Vahdat ، Heshmatollah Alinezhad ، Mohammad Norouzi

Abstract

A novel, green and reusable nano ionic liquid and catalyst, namely 1-methylimidazolium trinitromethanide {[HMIM]C(NO2)3}, was designed and fully characterized by 1H NMR, 13C NMR, IR, mass, X-ray diffraction patterns (XRD) and Transmission electron microscopy (TEM) analysis. The catalytic application of the presented catalyst was successfully tested on the Hantzsch four-component reaction of various aromatic aldehydes, 1,3-dione, b-ketoester and ammonium acetate at room temperature under solventfree and mild conditions to give the polyhydroquinoline derivatives in good to excellent yields. In the presented work, some products have been reported for the first time.