1403/01/09
حشمت اله علی نژاد

حشمت اله علی نژاد

مرتبه علمی: استاد
ارکید:
تحصیلات: دکترای تخصصی
اسکاپوس:
دانشکده: دانشکده شیمی
نشانی:
تلفن: 9111144735

مشخصات پژوهش

عنوان
Pd nanoparticles catalyst supported on TMU-16-NH 2 metal-organic framework for Sonogashira cross-coupling reaction
نوع پژوهش
JournalPaper
کلیدواژه‌ها
Metal-organic frameworks Post-synthetic modification Sonogashira coupling reaction
سال
2022
مجله JOURNAL OF ORGANOMETALLIC CHEMISTRY
شناسه DOI
پژوهشگران Ameneh Kiani ، Heshmatollah Alinezhad ، Shahram Ghasemi

چکیده

The current article presented the synthesis and characterization of a novel, unique, and effective hetero- geneous catalytic system, based on a metal-organic framework named Pd@TMU-16-NH 2 with high cat- alytic performance. Also, the application of this catalyst was investigated successfully in the Sonogashira coupling reaction of various aryl halides (I, Br, Cl) with phenylacetylene. This reaction was carried out in EtOH with good to excellent yields in the presence of just 1.5 mol% of the catalyst under mild conditions. Stability, recovery, reusability, high yield products, and short reaction time are some of the noteworthy characteristics of the Pd@TMU-16-NH 2 nanocatalyst. These properties can decrease pollution to obtain the standards of green chemistry.