1403/01/30

رضا اوجانی

مرتبه علمی: استاد
ارکید:
تحصیلات: دکترای تخصصی
اسکاپوس:
دانشکده: دانشکده شیمی
نشانی:
تلفن: 011 35302350

مشخصات پژوهش

عنوان
Facile synthesis of polyoxometalate-based composite with doped ternary NiCoFe cations as electrocatalyst for oxygen evolution reaction
نوع پژوهش
JournalPaper
کلیدواژه‌ها
Organic-inorganic composite Tri-metallic catalyst Oxygen evolution reaction Phosphotungstic acid Alkaline medium
سال
2021
مجله INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
شناسه DOI
پژوهشگران Ali Hossein Imani ، Reza Ojani ، Jahan Bakhsh Raoof

چکیده

The construction of efficient and low-cost electrocatalysts for oxygen evolution reactions (OER) to replace precious catalysts is a necessity to achieve economic production of hydrogen. Herein, we report an efficient tri-metallic electrocatalysts for the OER that is prepared by incorporate nickel, cobalt and iron cations on Triton X-100/phosphotungstic acid organic-inorganic composite without utilize any binders or energy consumer procedure. Considering to the synergy effect of simultaneous absorption of NiCoFe cations on composite substrate, the as-made tri-metallic catalyst exhibits excellent OER activity with a small overpotential of 210 and 330 mV at a current density of 10 and 100 mA cm2, respectively. Moreover, remarkable trends in electrocatalytic activity of mono-, bi- and trimetallic electrocatalysts at low (10 mA) and high (100 mA) current density are observed. In addition, this new families of non-precious metal catalyst shows long-term durability in 1 M KOH.