2024 : 12 : 22
Behrooz Maleki

Behrooz Maleki

Academic rank: Professor
ORCID:
Education: PhD.
ScopusId:
HIndex:
Faculty: Faculty of Chemistry
Address: University of Mazandaran
Phone: 01135303102

Research

Title
Synthesis and Characterization of a Novel Crowned Schiff Base Ligand Linked to Ionic Liquid and Application of Its Mn(III) Complex in the Epoxidation of Olefins
Type
JournalPaper
Keywords
Schiff base Ionic liquid Crown ether Oxone Epoxidation
Year
2023
Journal Chemical Methodologies
DOI
Researchers Sanaz Naderi ، Reza Sandaroos ، Sahar Peyman ، Behrooz Maleki

Abstract

A new Schiff base ligand bound to ionic liquid and crown ether was synthesized and complexed with Mn (III) metal. Manganese complex was used in the vicinity of oxone oxidant and the absence of an axial base in water-chloroform biphasic oxidation to oxidize different alkenes, the corresponding epoxides were obtained with 70-96% yields. The lowest efficiency is related to alkenes with electron-withdrawing groups