2024 : 11 : 21

Abbas FarhadiKoutenaei

Academic rank: Assistant Professor
ORCID:
Education: PhD.
ScopusId:
HIndex: 0/00
Faculty: Science
Address:
Phone: 011-35302494

Research

Title
2-Amino-5-methylpyridium 2-aminobenzoate
Type
JournalPaper
Keywords
single-crystal X-ray study, T=100 K, mean σ(C-C)=0.002 Å, R factor = 0.037, wR factor = 0.101, data-to-parameter ratio 14.7.
Year
2012
Journal Acta Crystallographica Section E: Structure Reports Online
DOI
Researchers Kaliyaperumal Thanigaimani ، Abbas FarhadiKoutenaei ، Nuridayanti Che Khalib ، ُSuhana Arshed ، َAbdul Razak Ibrahim

Abstract

In the 2-aminobenzoate anion of the title salt, C6H9N2+·C7H6NO2−, an intramolecular N—H⋯O hydrogen bond is observed. The dihedral angle between the ring and the CO2 group is 8.41 (13)°. In the crystal, the protonated N atom and the 2-amino group of the cation are hydrogen bonded to the carboxylate O atoms via a pair of N—H⋯O hydrogen bonds, forming an R22(8) ring motif. The ion pairs are further connected via N—H⋯O hydrogen bonds, resulting in a donor–donor–acceptor–acceptor (DDAA) array of quadruple hydrogen bonds. The crystal structure also features a weak N—H⋯O hydrogen bond and a C—H⋯π interaction, resulting in a three-dimensional network.