1403/02/04

عباس فرهادی کوتنایی

مرتبه علمی: استادیار
ارکید:
تحصیلات: دکترای تخصصی
اسکاپوس:
دانشکده: دانشکده علوم پایه
نشانی:
تلفن: 011-35302494

مشخصات پژوهش

عنوان
2-Amino-5-methylpyridinium 3-hydroxypyridine-2-carboxlate
نوع پژوهش
JournalPaper
کلیدواژه‌ها
single-crystal X-ray study, T=100 K, mean σ(C-C)=0.001 Å, R factor = 0.036, wR factor = 0.115, data-to-parameter ratio 23.0.
سال
2013
مجله Acta Crystallographica Section E: Structure Reports Online
شناسه DOI
پژوهشگران Abbas FarhadiKoutenaei ، Kaliyaperumal Thanigaimani ، ُSuhana Arshed ، َAbdul Razak Ibrahim

چکیده

In the 3-hy­droxy­picolinate anion of the title salt, C6H9N2 +·C6H4NO3 −, an intra­molecular O—H⋯O hydrogen bond with an S(6) graph-set motif is formed, so that the anion is essentially planar, with a dihedral angle of 9.55 (9)° between the pyridine ring and the carboxyl­ate group. In the crystal, the cations and anions are linked via N—H⋯O hydrogen bonds, forming a centrosymmetric 2 + 2 aggregate with R 2 2(8) and R 4 2(8) ring motifs. The crystal structure also features N—H⋯N and weak C—H⋯π inter­actions.