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Niaz Monadi

Niaz Monadi

Academic rank: Assistant Professor
ORCID:
Education: PhD.
ScopusId:
Faculty: Faculty of Chemistry
Address:
Phone: 01135302508

Research

Title
A molybdenum(VI) Schiff base complex immobilized on functionalized Fe3O4 nanoparticles as a recoverable nanocatalyst for synthesis of 2-amino-4Hbenzo[ h]chromenes
Type
JournalPaper
Keywords
Dioxomolybdenum(VI) complex, Three-component, Fe3O4
Year
2018
Journal TRANSITION METAL CHEMISTRY
DOI
Researchers Niaz Monadi ، Elham Moradi Kharmanani

Abstract

A dioxomolybdenum(VI) complex of a Schiff base, immobilized on the surface of modified Fe3O4 with a silica coating, has been synthesized and characterized by spectroscopic and microscopic techniques including FTIR, TGA, ICP, SEM, EDX, VSM, and XRD analyses. The catalytic performance of this material has been evaluated for the preparation of 2-amino-4Hbenzo[ h]chromenes via the one-pot, three-component reaction of aldehydes, malononitrile, and 1-naphthol under solventfree conditions. The benefits of this protocol are short reaction time, simple workup procedure, and high yields of products. Also, the synthesized nanocatalyst could be separated easily from the reaction mixture using an external magnet and reused for four consecutive times with only minor degradation of its catalytic performance.