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Mojtaba Mohseni

Mojtaba Mohseni

Academic rank: Associate Professor
ORCID: 0000-0002-5709-6600
Education: PhD.
ScopusId: 55937730000
HIndex: 17/00
Faculty: Science
Address: Department of Microbiology, School of Biosciences, University of Mazandaran, Babolsar, IRAN
Phone: +98-11-3530-2497

Research

Title
Synthesis, crystal structure, and antimicrobial activity of bis((2-(2-aminoethyl)imino-3-utanone oxime)copper(II) perchlorate
Type
JournalPaper
Keywords
Copper(II) complex; Crystal structure; Tridentate ligand; Synthesis; Imine oxime; Antibacterial activity
Year
2014
Journal Journal of Coordination Chemistry
DOI
Researchers Hamid Golchoubian ، Ommeleila Nazari ، Mojtaba Mohseni

Abstract

Copper(II) complex of an unsymmetrical tridentate ligand containing oxime, imine, and amine donors was synthesized with a condensation between diacetylmonoxime and ethylenediamine in the presence of copper(II) perchlorate. The complex is characterized by elemental analysis, IR, UV–vis, molar conductance, thermogravimetry, and single-crystal X-ray diffraction. The cation consists of two tridentate 2-(2-aminoethyl)imino-3-butanone oxime with coordination sphere of CuN6 type. The geometry around copper(II) is distorted octahedral with two amine donors, two imine, and two nitrogens of the oxime. Photoluminescence reveals that the complex exhibits strong fluorescent emission in acetonitrile at room temperature. The antibacterial activity of the complex was also studied.