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Behrooz Maleki

Behrooz Maleki

Academic rank: Professor
ORCID:
Education: PhD.
ScopusId:
Faculty: Faculty of Chemistry
Address: University of Mazandaran
Phone: 01135303102

Research

Title
Caesium carbonate supported on hydroxyapatite-encapsulated Ni0.5Zn0.5Fe2O4 nanocrystallites as a novel magnetically basic catalyst for the one-pot synthesis of pyrazolo[1,2-b]phthalazine-5,10-diones
Type
JournalPaper
Keywords
Ni0.5Zn0.5Fe2O4 magnetic nanoparticle-supported caesium carbonate; 1H-pyrazolo[1,2-b]phthalazine-5,10-diones; aldehydes; malononitrile; ethyl cyanoacetate; phthalhydrazide; green chemistry
Year
2015
Journal Applied Organometallic Chemistry
DOI
Researchers Behrooz Maleki ، Samaneh Barat Nam Chalaki ، Samaneh Sedigh Ashrafi ، esmaeil rezaei seresht ، Farid Moeinpour ، Amir Khojastehnezhad ، Reza Tayebee

Abstract

A novel nanomagnetic basic catalyst of caesium carbonate supported on hydroxyapatite-coated Ni0.5Zn0.5Fe2O4 magnetic nano- particles (Ni0.5Zn0.5Fe2O4@HAP-Cs2CO3) was prepared. This new catalyst was fully characterized using Fourier transform infrared spectroscopy, transmission and scanning electron microscopy, X-ray diffraction and vibrating sample magnetometry techniques, and then the catalytic activity of this catalyst was investigated in the synthesis of 1H-pyrazolo[1,2-b]phthalazine-5,10-dione deriv- atives. Also, Ni0.5Zn0.5Fe2O4@HAP-Cs2CO3 could be reused at least five times without significant loss of activity and could be recov- ered easily by applying an external magnet. Thus, the developed nanomagnetic catalyst is potentially useful for the green and economic production of organic compounds.